| Fixture | Kick-Off | |
|---|---|---|
| Arsenal 2-0 Olympiakos | 01/10/2025 20:00:00 | Preds |
| Atalanta 2-1 Club Brugge | 30/09/2025 17:45:00 | Preds |
| Atlético Madrid 5-1 Eintracht Frankfurt | 30/09/2025 20:00:00 | Preds |
| Barcelona 1-2 Paris SG | 01/10/2025 20:00:00 | Preds |
| Bayer 04 Leverkusen 1-1 PSV Eindhoven | 01/10/2025 20:00:00 | Preds |
| Bodø/Glimt 2-2 Tottenham Hotspur | 30/09/2025 20:00:00 | Preds |
| Borussia Dortmund 4-1 Athletic Bilbao | 01/10/2025 20:00:00 | Preds |
| Chelsea 1-0 Benfica | 30/09/2025 20:00:00 | Preds |
| Galatasaray 1-0 Liverpool | 30/09/2025 20:00:00 | Preds |
| Internazionale 3-0 Slavia Prague | 30/09/2025 20:00:00 | Preds |
| Kairat Almaty 0-5 Real Madrid | 30/09/2025 17:45:00 | Preds |
| Marseille 4-0 Ajax | 30/09/2025 20:00:00 | Preds |
| Monaco 2-2 Manchester City | 01/10/2025 20:00:00 | Preds |
| Napoli 2-1 Sporting CP | 01/10/2025 20:00:00 | Preds |
| Pafos 1-5 Bayern Munich | 30/09/2025 20:00:00 | Preds |
| Qarabag 2-0 FC Copenhagen | 01/10/2025 17:45:00 | Preds |
| Union Saint-Gilloise 0-4 Newcastle United | 01/10/2025 17:45:00 | Preds |
| Villarreal 2-2 Juventus | 01/10/2025 20:00:00 | Preds |
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