| Fixture | Kick-Off | |
|---|---|---|
| Arsenal 4-0 Atlético Madrid | 21/10/2025 20:00:00 | Preds |
| Atalanta 0-0 Slavia Prague | 22/10/2025 20:00:00 | Preds |
| Athletic Bilbao 3-1 Qarabag | 22/10/2025 17:45:00 | Preds |
| Barcelona 6-1 Olympiakos | 21/10/2025 17:45:00 | Preds |
| Bayer 04 Leverkusen 2-7 Paris SG | 21/10/2025 20:00:00 | Preds |
| Bayern Munich 4-0 Club Brugge | 22/10/2025 20:00:00 | Preds |
| Chelsea 5-1 Ajax | 22/10/2025 20:00:00 | Preds |
| Eintracht Frankfurt 1-5 Liverpool | 22/10/2025 20:00:00 | Preds |
| FC Copenhagen 2-4 Borussia Dortmund | 21/10/2025 20:00:00 | Preds |
| Galatasaray 3-1 Bodø/Glimt | 22/10/2025 17:45:00 | Preds |
| Kairat Almaty 0-0 Pafos | 21/10/2025 17:45:00 | Preds |
| Monaco 0-0 Tottenham Hotspur | 22/10/2025 20:00:00 | Preds |
| Newcastle United 3-0 Benfica | 21/10/2025 20:00:00 | Preds |
| PSV Eindhoven 6-2 Napoli | 21/10/2025 20:00:00 | Preds |
| Real Madrid 1-0 Juventus | 22/10/2025 20:00:00 | Preds |
| Sporting CP 2-1 Marseille | 22/10/2025 20:00:00 | Preds |
| Union Saint-Gilloise 0-4 Internazionale | 21/10/2025 20:00:00 | Preds |
| Villarreal 0-2 Manchester City | 21/10/2025 20:00:00 | Preds |
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